[2-(1H-Indol-4-yl)ethyl]dipropylamine

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[2-(1H-Indol-4-yl)eth­yl]dipropyl­amine

In the title compound, C(16)H(24)N(2), the aliphatic amine substituent is rotated almost orthogonally [C-C-C-C torsion angle = 75.7 (3)°] out of the plane of the indole unit. The amine N atom has a pyramidal configuration deviating by 0.380 (3) Å from the plane of the adjacent C atoms. All of the aliphatic groups are in extended transoid conformations. In the crystal, mol-ecules form chains alo...

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2-[2-(1H-indol-3-yl)ethyl­iminiomethyl]-4-nitro­phenolate

The title Schiff base, C(17)H(15)N(3)O(3), exists in the zwitterionic form with the phenol H atom transferred to the imine group. Adjacent zwitterions are linked into a linear chain running along the a axis by an indole-hydr-oxy N-H⋯O hydrogen bond [3.100 (2) Å].

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2-(4-Bromo-1H-indol-3-yl)acetonitrile

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(4-Bromo­phen­yl)(1-phenyl­sulfonyl-1H-indol-2-yl)methanone

In the title compound, C(21)H(14)BrNO(3)S, the indole ring system forms dihedral angles of 65.64 (8) and 59.30 (8)°, respectively, with the phenyl and bromo-phenyl rings. In the crystal, mol-ecules are connected by a C-H⋯O hydrogen bond, forming a chain along [101]. The chains are further connected by weak inter-molecular C-H⋯π inter-actions, forming a layer parallel to the ac plane.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812015474